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Zare, AAuthorNogalska, AAuthorPuga, AAuthorGiamberini, MCorresponding Author
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Article

Modified polyethyleneimine as additive for enhanced direct air capture via membrane contactors

Publicated to:Journal Of Co2 Utilization. 78 102629- - 2023-12-01 78(), DOI: 10.1016/j.jcou.2023.102629

Authors: Zare, Alireza; Boukalfa, Ahmed Khatib; Nogalska, Adrianna; Puga, Alberto; Cerruti, Pierfrancesco; Pascual-Jose, Borja; Ribes-Greus, Amparo; Giamberini, Marta

Affiliations

Eurecat, Ctr Tecnol Catalunya, C Marcelli Domingo 2 - Author
Natl Council Res, Inst Polymers Composites & Biomat, Via Campi Flegrei 34 - Author
Univ Politecn Valencia UPV, Inst Technol Mat ITM, Cami Vera S-N - Author
Univ Rovira & Virgili, Dept Chem Engn, Ave Paisos Catalans 26 - Author

Abstract

This paper reports the preparation and characterization of asymmetric membranes for direct air capture (DAC) in polysulfone membrane contactors. In the previous studies it was found that blending the polysulfone with modified Lupasol G20 improved the polysulfone membrane performance; however, the hydrophobicity and stability of the additive require improvement for the application in gas/liquid system. In order to achieve this objective, in the current study, Lupasol G20 was grafted with phenyl isocyanate via urea linkages in a solvent-free and eco-friendly method. Membranes with different amount of the additive were prepared by phase inversion and characterized by several techniques in terms of morphology, porosity, wettability, and stability in aqueous KOH solution. Finally, CO2 solubility and mass transfer coefficient were determined and correlated with membranes' performance in the direct air capture device. In general, it was found that the presence of the additive greatly improved the characteristics of the membranes in terms of CO2 capture efficiency and robustness, outperforming the results obtained previously. The best results for were obtained with 5% additive content reaching 0.18 [mol/m2s].

Keywords
AbsorbentsAssimilationCarbon dioxideCo2Direct air captureHollow-fiber membranesMembrane contactorMorphologyPerformancePhenyl isocyanatePolyethylene iminePolysulfoneProgressRatesRemovalSeparation

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal Journal Of Co2 Utilization due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2023, it was in position 19/170, thus managing to position itself as a Q1 (Primer Cuartil), in the category Engineering, Chemical.

Independientemente del impacto esperado determinado por el canal de difusión, es importante destacar el impacto real observado de la propia aportación.

Según las diferentes agencias de indexación, el número de citas acumuladas por esta publicación hasta la fecha 2025-05-13:

  • WoS: 1
  • Scopus: 1
Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-05-13:

  • The use, from an academic perspective evidenced by the Altmetric agency indicator referring to aggregations made by the personal bibliographic manager Mendeley, gives us a total of: 10.
  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 10 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

  • The Total Score from Altmetric: 0.25.
  • The number of mentions on the social network X (formerly Twitter): 1 (Altmetric).

It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

  • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
  • Assignment of a Handle/URN as an identifier within the deposit in the Institutional Repository: http://hdl.handle.net/20.500.11797/imarina9366655
Leadership analysis of institutional authors

This work has been carried out with international collaboration, specifically with researchers from: Italy.

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Zare, Alireza) and Last Author (Giamberini, Marta).

the author responsible for correspondence tasks has been Giamberini, Marta.